How do you perform the assay of magnesium sulphate solution by complexometric titration?

Dilute to about 150 ml with DW, add to it sufficient ammonia buffer (pH 10.0) to dissolve the precipitate and add a further 5 ml quantity in excess. Finally add 50 mg of Mordant Black II mixture and titrate with the disodium edetate solution until the solution turns green.

How does complexometric titration determine magnesium sulphate?

Magnesium can be easily determined by EDTA titration in the pH 10 against Eriochrome Black T. If the solution initially contains also different metal ions, they should be removed or masked, as EDTA react easily with most cations (with the exception of alkali metals).

Which indicator is used in assay of magnesium sulphate?

The titration with 0.1 M MgSO4 solution is conducted in the presence of eriochrome black T solution as indicator, first time for eliminating the excess of EDTA added, and afterwards to determine the AsO4 3− ions, after adding about 40\% of ethanol.

How Mg2+ is estimated by EDTA?

Given the ratio of Ca2+ + Mg2+ : EDTA = 1 : 1, calculate the moles of Ca2+ and Mg2+ that must have been complexed with EDTA by subtracting the excess EDTA from the total moles of EDTA added to the sample. This result is the moles of Ca2+ and Mg2+ in the sample solution.

What is the purpose of adding mgcl2 6h2o in the preparation of EDTA solution?

EDTA Solution Magnesium chloride is added to enhance the sharpness of the endpoint (It forms a more stable complex with the indicator).

How do you identify magnesium sulfate?

Magnesium sulfate is available as brilliant colourless crystals, granular crystalline powder or white powder with a bitter salty cooling taste. Crystals effloresce in warm, dry air. It is freely soluble in water, very soluble in boiling water, and sparingly soluble in alcohol.

How do you perform a complexometric titration?

Fill the burette with EDTA solution. Now start titrating the mixture with standard EDTA solution. End point can be detected by color change from wine red to blue. Repeat the titration for three times to obtain 3 concordant readings.

How do you test for magnesium sulfate?

A check shall be made for the presence of magnesium sulfate in the wash water. Washing shall be considered complete when the addition of a few drops of a 10 percent Barium Chloride solution to a small sample of the wash water does not produce a cloudy white precipitate.

Why is mgcl2 6h2o added to a solution of EDTA?

How do you calculate magnesium from magnesium hardness?

The amount of hardness is expressed in milligrams per litre (mg/L) or grains per gallon (gpg) as calcium carbonate. Hardness is calculated from the equation Hardness = 2.497 (Ca) + 4.118 (Mg). Therefore, fluctuations in the magnesium pool affect hardness stronger than do calcium fluctuations.

What is MgCl2 6H2O?

Magnesium chloride hexahydrate (MgCl2.6H2O)

What is principle of assay for calcium gluconate?

Explanation: Assay— Dissolve about 800 mg of Calcium Gluconate, accurately weighed, in 150 mL of water containing 2 mL of 3 N hydrochloric acid. Add 15 mL of 1 N sodium hydroxide and 300 mg of hydroxy naphthol blue, and continue the titration to a blue endpoint.

How do you make magnesium sulfate 7-water in the laboratory?

You can make magnesium sulfate7-water in the laboratory by reacting magnesium – oxide with dilute sulfuric acid. Equipment and materials • Weighing bottle (or small beaker)

How is the hardness of calcium and magnesium measured?

Both the total hardness and the individual calcium and magnesium hardnesses will be measured. EDTA and the metallochromic indicators used are involved in complexation reactions with the magnesium and calcium ions that are responsible for water hardness.

How do you determine the hardness of water by titration?

Determination of Water Hardness using Complexometric titration. You will use EDTA complexometric titration to determine the hardness of a sample of water brought from your home. Both the total hardness and the individual calcium and magnesium hardnesses will be measured.

What is the reaction between EDTA and magnesium chloride?

A back titration is carried out using a solution of magnesium chloride. This forms a complex with the excess EDTA molecules until the end-point, when all the excess EDTA has been complexed. The remaining magnesium ions of the magnesium chloride solution then start to complex with ErioT indicator, immediately The main reaction is