Table of Contents
- 1 How do you know if a compound is aromatic?
- 2 What does it mean when a compound is aromatic?
- 3 What are the two effects that have to be considered to determine the influence a substituent will have?
- 4 What do you mean by aromaticity explain Huckel’s theory of aromaticity?
- 5 What is the structure of aromatic hydrocarbon?
How do you know if a compound is aromatic?
Explanation: For a compound to be considered aromatic, it must be flat, cyclic, and conjugated and it must obey Huckel’s rule. Huckel’s rule states that an aromatic compound must have pi electrons in the overlapping p orbitals in order to be aromatic (n in this formula represents any integer).
What are the two effects that have to be considered to determine the influence a substituent will have on electrophilic aromatic substitution *?
1. Resonance and electronic 2.
What does a double bond indicate?
A double bond is a type of chemical bond in which two electron pairs are shared between two atoms. Double bonds are shorter and stronger than single bonds. Double bonds are drawn as two parallel lines in chemical structure diagrams. The equal sign is used to indicate a double bond in a formula.
What does it mean when a compound is aromatic?
aromatic compound, any of a large class of unsaturated chemical compounds characterized by one or more planar rings of atoms joined by covalent bonds of two different kinds. The unique stability of these compounds is referred to as aromaticity.
What is aromatic functional group?
Aromatics. The additional functional group that contains only carbon and hydrogen is an aromatic ring which is a six-carbon ring with alternative double bonds. The aromatic ring is also shown as a ring with a circle in the middle representing the double bonds. 2: Aromatic rings contain alternating double bonds.
How is pyrrole aromatic?
Pyrrole is cyclic and conjugated (that lone pair on nitrogen can contribute to the pi-system). There are two pi bonds and one lone pair of electrons that contribute to the pi system. This gives us 6 total pi electrons, which is a Huckel number (i.e. satisfies 4n+2). Therefore it’s aromatic.
What are the two effects that have to be considered to determine the influence a substituent will have?
Introduction. There are two main effects of substituents. The substituent will affect the rate of reaction (aka reactivity) of the ring, and it will also affect the position of attack (called “directing effects”) on the ring by the incoming electrophile.
What is substituent effect?
Substituent effects are the changes on a reaction or property in the unchanged part of the molecule resulting from substituent variation. Some Reactions or Properties.
What is meant by double bond or double covalent bond?
A double covalent bond is where two pairs of electrons are shared between the atoms rather than just one pair. Some simple molecules containing double bonds. Oxygen, O2. Two oxygen atoms can both achieve stable structures by sharing two pairs of electrons as in the diagram.
What do you mean by aromaticity explain Huckel’s theory of aromaticity?
What is Huckel rule of aromaticity? A molecule should have a certain number of lone pairs of electrons within p orbitals or electrons with pi bonds within a closed loop of adjacent, parallel p orbitals in order to become aromatic.
Is an R group a functional group?
The R-group concept is flexible. All three of these group are also functional groups. Quoting Wikipedia, “functional groups are specific groups (moieties) of atoms or bonds within molecules that are responsible for the characteristic chemical reactions of those molecules.
What is an example of a hydrocarbon with double bonds?
Examples Ethylene (C 2 H 4) is a hydrocarbon with a double bond between the two carbon atoms. Other alkenes also contain double bonds. Double bonds are seen in imine (C=N), sulfoxides (S=O), and azo compounds (N=N).
What is the structure of aromatic hydrocarbon?
Aromatic hydrocarbons contain the 6-membered benzene ring structure (A) that is characterized by alternating double bonds. Ultradur, PBT is a plastic polymer that contains an aromatic functional group.
What is the structure of aromatic hydrocarbon in PBT?
Aromatic hydrocarbons contain the 6-membered benzene ring structure (A) that is characterized by alternating double bonds. Ultradur, PBT is a plastic polymer that contains an aromatic functional group. The repeating monomer of Ultradur is shown in (B).
What is a double bond in chemistry?
Updated September 08, 2017. A double bond is a type of chemical bond in which two electron pairs are shared between two atoms. This type of bond involves four bonding electrons between atoms, rather than the usual two bonding electrons involved in a single bond. Because of the large number of electrons, double bonds tend to be reactive.