Is ethyl carbocation more stable than isopropyl carbocation?

Shown below are the resonance forms of the isopropyl carbocation (2), a secondary carbocation. Thus, the net charge of +1 is delocalized over a greater number of atoms in the isopropyl carbocation than in the ethyl carbocation. The isopropyl carbocation should, therefore, be more stable than the ethyl carbocation.

Which is more stable ethyl or propyl carbocation?

Which is more stable propyl carbocation or ethyl carbocation? The greater number of alkyl groups with +I effect tend to increase the electron density on the positively charged carbon atom and dispers ethe charge on it.So propyl carbocation is more stable.

Which is more stable ethyl carbocation?

Benzyl carbocation is more stable than ethyl carbocation.

Which is more stable methyl carbocation or ethyl carbocation?

Ethyl carbocation is more stable than methyl carbocation as the ethyl carbocation is surrounded by 1 more carbon atom. Whereas there is no such carbon atom with methyl carbocation and is highly unstable.

What is the most stable carbocation?

Benzylic carbocations
Benzylic carbocations are so stable because they have not one, not two, but a total of 4 resonance structures. This shares the burden of charge over 4 different atoms, making it the MOST stable carbocation.

Which carbocation is more stable one here?

Three main factors increase the stability of carbocations: Increasing the number of adjacent carbon atoms: methyl (least stable carbocation) < primary < secondary < tertiary (most stable carbocation)

Which carbocation is most stable in the following?

A tertiary carbocation is the most stable carbocation due to the electron releasing effect of three methyl groups.

Why is ethyl cation more stable than methyl cation?

Ethyl carbocation is more stable than methyl carbocation because the former is substituted with another carbon atom which is hence stable by inductive and hyperconjugation effect.

How does carbocation compare to stability?

What this means is that, in general, more substituted carbocations are more stable: a tert-butyl carbocation, for example, is more stable than an isopropyl carbocation. Primary carbocations are highly unstable and not often observed as reaction intermediates; methyl carbocations are even less stable.

Why are more substituted carbocations more stable?

Generally, the more highly substituted a carbocation is, the more stable it is. There are a number of ways to explain why this is true. Simply put, the order of carbocation stability matches the number of carbons bonded to the cationic carbon, with higher numbers leading to greater stability.

Which of the following carbocation is most stable?

tertiary carbocation
A tertiary carbocation is the most stable carbocation due to the electron releasing effect of three methyl groups.

Is the ethyl cation more stable than allyl and benzyl carbocations?

My book appears to state that the ethyl cation (a primary carbocation) is more stable than both allyl and benzyl carbocations. I knew that cation stability depends on the following factors: resonance > hyperconjugation > +inductive effect.

What is the difference in stability between carbocations and free radicals?

The difference in stability between carbocations is much larger than between free radicals. The tert butyl radical is only 12 Kcal more stable than methyl free radical and hence depend upon the substrate with 66 – 72 Kcal more stable than the methyl cation.

Why is a tertiary butyl carbocation more stable than a secondary butyl carbocation?

>> A tertiary butyl carbocatio… A tertiary butyl carbocation is more stable than a secondary butyl carbocation because of which of the following? Tertiary carbocations are stable due to inductive effect ( +I effect of alkyl groups) and hyperconjugation.

Which one is more stable ethyl or methyl?

C X 2 H X 5 X + v s C X 3 H X 7 X + There are two conflicting trends here. Inductive effect of ethyl will be higher than that of methyl so carbocation attached to ethyl (3 carbons in total) should be more stable.